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Yttrium(III) chloride

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Yttrium(III) chloride
Yttrium(III) Chloride
Yttrium(III) Chloride
Names
IUPAC names Yttrium(III) chloride
Yttrium trichloride
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.716 Edit this at Wikidata
RTECS number
  • ZG3150000
CompTox Dashboard (EPA)
InChI
  • InChI=1S/3ClH.Y/h3*1H;/q;;;+3/p-3Key: PCMOZDDGXKIOLL-UHFFFAOYSA-K
  • InChI=1/3ClH.Y/h3*1H;/q;;;+3/p-3Key: PCMOZDDGXKIOLL-DFZHHIFOAW
SMILES
  • Cl(Cl)Cl
Properties
Chemical formula YCl3
Molar mass 195.26 g/mol
Appearance white solid
Density 2.67 g/cm
Melting point 721 °C
Boiling point 1507 °C
Solubility in water 82 g/100 mL
Solubility 60.1 g/100 mL ethanol (15°C)
60.6 g/100 mL pyridine (15°C)
Structure
Crystal structure Monoclinic, mS16
Space group C12/m1, No. 12
Hazards
Flash point Non-flammable
Related compounds
Other anions Yttrium(III) fluoride
Yttrium(III) bromide
Yttrium(III) iodide
Other cations Scandium(III) chloride
Lanthanum(III) chloride
Actinium(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Yttrium(III) chloride (YCl3) is an ionic compound of yttrium and chlorine. It is a salt that is solid at room temperature, highly soluble in water, and deliquescent. YCl3 in the solid state has a crystal structure with cubic close packed chloride ions and yttrium ions filling one third of the octahedral holes and the resulting YCl6 octahedra sharing three edges with adjacent octahedra give a layer structure. This structure is shared by a range of compounds notably AlCl3.
YCl3 is used as a catalyst and in superconductors and has been linked to pulmonary edema and liver damage .

Reactions

Yttrium(III) chloride can be formed by reacting yttrium(III) oxide with hydrochloric acid, among other methods.

References

  1. ^ Yttrium & Compounds, United States Occupational Safety and Health Administration, 2007-01-11, retrieved 2008-05-29
  2. ^ Spencer, James F. (1919), The Metals of the Rare Earths, New York: Longmans, Green, and Co, p. 135, retrieved 2008-05-29
  3. Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6
  4. Gangolli, S. (1999), The Dictionary of Substances and Their Effects, London: Royal Society of Chemistry, pp. 666–7, ISBN 9780854048380, retrieved 2008-05-29
  5. Turner, Jr., Francis M.; Berolzheimer, Daniel D.; Cutter, William P.; Helfrich, John (1920), The Condensed Chemical Dictionary, New York: Chemical Catalog Company, p. 492, retrieved 2008-05-29
Yttrium compounds
Yttrium(II)
Yttrium(III)
Organoyttrium(III) compounds
  • Y(C5H5)3
  • Y2(C2O4)3

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