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Gadolinium(III) selenate

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Gadolinium(III) selenate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
InChI
  • InChI=1S/2Gd.3H2O4Se/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6Key: LSEBDKBNNFPZKP-UHFFFAOYSA-H
SMILES
  • (=O)(=O).(=O)(=O).(=O)(=O)..
Properties
Chemical formula Gd2(SeO4)3
Molar mass 743.395
887.523 (octahydrate)
Density 3.309g/cm (octahydrate)
Solubility in water soluble
Related compounds
Other anions gadolinium(III) selenite
gadolinium(III) sulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references
Chemical compound

Gadolinium(III) selenate is an inorganic compound with the chemical formula Gd2(SeO4)3. It exists as the anhydrate and octahydrate. The octahydrate transforms into the anhydrate when heated to 130 °C.

Preparation

Gadolinium(III) selenate can be obtained by crystallizing from the reaction of gadolinium oxide and selenic acid solution:

Gd2O3 + 3 H2SeO4 → Gd2(SeO4)3 + 3 H2O

References

  1. 化学化工物性数据手册(无机卷).刘光启 等主编.化学工业出版社.16.2 硒酸盐.P569
  2. Perkovskaya, Yu. B.; Sukhanova, I. M. Rare earth metal selenates. Metody Polucheniya Khimicheskikh Reaktivov i Preparatov, 1967. 16: 120-123. ISSN: 0539-5143.
Gadolinium compounds
Gadolinium(III)
Organogadolinium(III)
  • Gd(C5H7O2)3
  • Salts and covalent derivatives of the selenate ion
    H2SeO4 He
    Li2SeO4 Be B C (NH4)2SeO4 O F Ne
    Na2SeO4 MgSeO4 Al2(SeO4)3 Si P S Cl Ar
    K2SeO4 CaSeO4 Sc Ti V Cr Mn FeSeO4
    Fe2(SeO4)3
    CoSeO4 NiSeO4 CuSeO4 ZnSeO4 Ga2(SeO4)3 Ge As SeO4 Br Kr
    Rb2SeO4 Sr Y Zr(SeO4)2 Nb Mo Tc Ru Rh Pd Ag2SeO4 CdSeO4 In Sn Sb Te I Xe
    Cs2SeO4 BaSeO4 * Lu2(SeO4)3 Hf(SeO4)2 Ta W Re Os Ir Pt Au2(SeO3)2(SeO4) Hg Tl PbSeO4 Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * La2(SeO4)3 Ce2(SeO4)3
    Ce(SeO4)2
    Pr2(SeO4)3 Nd Pm Sm2(SeO4)3 Eu Gd2(SeO4)3 Tb Dy2(SeO4)3 Ho2(SeO4)3 Er2(SeO4)3 Tm2(SeO4)3 Yb2(SeO4)3
    ** Ac Th(SeO4)2 Pa U Np Pu Am Cm Bk Cf Es Fm Md No
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