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Bromo(tetrahydrothiophene)gold(I)

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Bromo(tetrahydrothiophene)gold(I)
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
PubChem CID
InChI
  • InChI=1S/C4H8S.Au.BrH/c1-2-4-5-3-1;;/h1-4H2;;1H/q;+1;/p-1Key: DVTPJQDAZYEPPF-UHFFFAOYSA-M
SMILES
  • Br1CCCC1
Properties
Chemical formula C4H8AuBrS
Molar mass 365.04 g·mol
Related compounds
Related compounds chloro(tetrahydrothiophene)gold(I), chloro(dimethyl sulfide)gold(I)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). checkverify (what is  ?) Infobox references
Chemical compound

Bromo(tetrahydrothiophene)gold(I) is a coordination complex of gold. It is related to the more commonly used chloro(tetrahydrothiophene)gold(I). Similarly, the tetrahydrothiophene ligand is labile and is readily substituted with other stronger ligands, to give linear gold bromide complexes.

This compound may be prepared by reaction of tetrabromoauric acid (formed from tetrachloroauric acid and hydrobromic acid) with tetrahydrothiophene.

References

  1. Eiter, Lauren C.; Hall, Nathan W.; Day, Cynthia S.; Saluta, Gilda; Kucera, Gregory L.; Bierbach, Ulrich (2009). "Gold(I) Analogues of a Platinum–Acridine Antitumor Agent are only Moderately Cytotoxic but Show Potent Activity Against Mycobacterium Tuberculosis". Journal of Medicinal Chemistry. 52 (21): 6519–22. doi:10.1021/jm9012856. PMC 3176588. PMID 19803526.
Gold compounds
Gold(-I)
Gold(I)
Organogold(I) compounds
  • (AuC6H2(CH3)3)5
  • (C2H5)3PAuSC5H5O(CO2CH3)3CH2OCOCH3
  • AuSC5H5O(OH)3CH2OH
  • NaAuSCH2CHOHCH2SO3
  • BrAuSC4H8
  • ClAuSC4H8
  • ClAuS(CH3)2
  • ClAuP(C6H5)3
  • Na2AuSCHCO2CH2CO2
  • NaAuSCHCO2CH2CO2H
  • Gold(II)
    Gold(I,III)
    Gold(III)
    Aurates(III)
  • HAuCl4
  • NaAuCl4
  • HAuBr4
  • HAu(NO3)4
  • ClO2Au(ClO4)4
  • NaAuO2
  • Gold(V)
    Gold(VI)
    Sulfur compounds
    Sulfides and
    disulfides
    Sulfur halides
    Sulfur oxides
    and oxyhalides
    Sulfites
    Sulfates
    Sulfur nitrides
    Thiocyanates
    Organic compounds
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