Revision as of 06:13, 19 April 2011 editCheMoBot (talk | contribs)Bots141,565 edits Updating {{chembox}} (no changed fields - added verified revid - updated 'UNII_Ref', 'ChemSpiderID_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEMBL_Ref', 'KEGG_Ref') per Chem/Drugbox validation (← Previous edit |
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{{chembox |
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{{Chembox |
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| Verifiedfields = changed |
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| verifiedrevid = 383524762 |
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| Watchedfields = changed |
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| Name = Trimethylstibine |
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| verifiedrevid = 424813681 |
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| ImageFile = Trimethylstibine annotated.png |
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| ImageFile = Trimethylstibine annotated.png |
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| ImageFile_Ref = {{chemboximage|correct|??}} |
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| ImageSize = |
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| ImageSize = 244 |
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| ImageName = Trimethylstibine |
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| ImageAlt = Stereo, skeletal formula of trimethylstibine with all explicit hydrogens added and some measurements |
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| IUPACName = Trimethylstibane |
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| ImageFile1 = Trimethylstibine-3D-spacefill.png |
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| OtherNames = |
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| ImageSize1 = 180 |
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| Section1 = {{Chembox Identifiers |
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| ImageAlt1 = Space-filling model of the trimethylstibine molecule |
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| SystematicName = Trimethylstibane<ref>{{Cite web|title = trimethylantimony - PubChem Public Chemical Database|url = https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=11656&loc=ec_rcs|work = The PubChem Project|publisher = National Center for Biotechnology Information|access-date = 25 September 2011|location = USA|date = 26 March 2005|at = Descriptors Computed from Structure}}</ref> |
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|Section1={{Chembox Identifiers |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 594-10-5 |
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| CASNo = 594-10-5 |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| CASNo_Ref = |
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| CASOther = |
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| UNII = E9DPM35Z2K |
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| RTECS = |
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| PubChem = 11656 |
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| EINECS = |
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| ChemSpiderID = 11166 |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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}} |
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| EINECS = 209-824-7 |
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| Section2 = {{Chembox Properties |
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| MeSHName = trimethylantimony |
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| Formula = C<sub>3</sub>H<sub>9</sub>Sb |
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| SMILES = C(C)C |
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| MolarMass = 166.863 g/mol |
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| StdInChI = 1S/3CH3.Sb/h3*1H3; |
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| Appearance = liquid |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| Density = 1.523 g/cm<sup>3</sup> at 15°C |
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| StdInChIKey = PORFVJURJXKREL-UHFFFAOYSA-N |
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| MeltingPt = -62°C |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| BoilingPt = 80.6°C |
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}} |
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| Solubility = insoluble |
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|Section2={{Chembox Properties |
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| SolubleOther = soluble in ], ], ]<ref name="hand"> |
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| Formula = {{Chem|C|3|SbH|9}} |
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{{Citation |
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| MolarMass = 166.86 g mol<sup>−1</sup> |
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| last = Lide |
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| Appearance = Colourless liquid |
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| first = David R. |
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| Density = 1.523 g cm<sup>−3</sup> (at 15°C) |
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| author-link = |
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| last2 = |
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| MeltingPtC = -62 |
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| first2 = |
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| BoilingPtC = 81 |
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}} |
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| author2-link = |
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|Section3={{Chembox Thermochemistry |
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| publication-date = |
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| DeltaHf = 24-26 kJ mol<sup>−1</sup> |
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| date = |
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| DeltaHc = -2.896--2.946 MJ mol<sup>−1</sup> |
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| year = 1998 |
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}} |
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| title = Handbook of Chemistry and Physics |
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|Section8={{Chembox Related |
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| edition = 87 |
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| OtherCompounds = ] <br/> ] <br/> ] <br/> ] <br/> ] |
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| volume = |
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}} |
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| series = |
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| publication-place = Boca Raton, FL |
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| place = |
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| publisher = CRC Press |
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| id = |
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| isbn = 0849305942 |
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| doi = |
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| oclc = |
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| pages = 3–558 |
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| url = |
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| accessdate = |
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}}</ref> |
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}} |
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| Section3 = {{Chembox Structure |
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| Coordination = |
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| CrystalStruct = |
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}} |
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| Section4 = {{Chembox Thermochemistry |
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| DeltaHf = |
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| DeltaHc = |
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| Entropy = |
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| HeatCapacity = |
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}} |
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| Section7 = {{Chembox Hazards |
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| ExternalMSDS = |
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| EUIndex = |
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| NFPA-H = |
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| NFPA-F = |
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| NFPA-R = |
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| RPhrases = |
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| SPhrases = |
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| FlashPt = |
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}} |
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| Section8 = {{Chembox Related |
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| OtherAnions = |
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| OtherCations = |
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}} |
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}} |
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}} |
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'''Trimethylstibine''' is a ] with the formula Sb(CH<sub>3</sub>)<sub>3</sub>. It is a colorless ] and toxic liquid<ref name="inorg"> |
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'''Trimethylstibine''' is an organoantimony compound with the formula Sb(CH<sub>3</sub>)<sub>3</sub>. It is a colorless ] and toxic liquid.<ref name="inorg"> |
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{{Citation |
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{{Citation |
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| last = Wiberg |
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| last1 = Wiberg |
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| first = Nils |
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| first1 = Nils |
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| author-link = |
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| author-link = |
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| last2 = Wiberg |
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| last2 = Wiberg |
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| first3 = A. F. |
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| first3 = A. F. |
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| author3-link = |
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| author3-link = |
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| publication-date = |
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| date = |
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| year = 2001 |
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| year = 2001 |
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| title = Inorganic Chemistry |
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| title = Inorganic Chemistry |
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| publisher = Academic Press |
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| publisher = Academic Press |
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| id = |
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| id = |
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| isbn = 0123526515 |
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| isbn = 0-12-352651-5 |
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| doi = |
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| doi = |
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| oclc = |
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| oclc = |
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| pages = 766 |
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| pages = 766 |
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| url = http://books.google.com/?id=Mtth5g59dEIC&pg=RA1-PA766&dq=Trimethylstibane |
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| url = https://books.google.com/books?id=Mtth5g59dEIC&q=Trimethylstibane&pg=RA1-PA766 |
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| accessdate = 2009-07-17 |
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| access-date = 2009-07-17 |
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}}</ref>. It is produced by anaerobic bacteria in ]-rich soils<ref name="organo"> |
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}}</ref> It is synthesized by treatment of ] and methyl ].<ref>Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. {{doi|10.1002/14356007.a03_055.pub2}}</ref> It is produced by anaerobic bacteria in ]-rich soils.<ref name="organo"> |
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{{Citation |
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{{Citation |
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| last = Craig |
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| last = Craig |
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| first = P. J. |
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| first = P. J. |
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| author-link = |
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| author-link = |
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| last2 = |
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| first2 = |
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| author2-link = |
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| last3 = |
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| first3 = |
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| author3-link = |
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| publication-date = |
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| date = |
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| year = 2003 |
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| year = 2003 |
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| title = Organometallic Compounds in the Environment |
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| title = Organometallic Compounds in the Environment |
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| publisher = Wiley and Sons |
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| publisher = Wiley and Sons |
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| id = |
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| id = |
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| isbn = 9780471899938 |
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| isbn = 978-0-471-89993-8 |
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| doi = |
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| doi = |
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| oclc = |
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| oclc = |
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| pages = 295 |
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| pages = 295 |
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| url = http://books.google.com/?id=Mtth5g59dEIC&pg=RA1-PA766&dq=Trimethylstibane |
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| url = https://books.google.com/books?id=Mtth5g59dEIC&q=Trimethylstibane&pg=RA1-PA766 |
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| accessdate = 2009-07-17 |
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| access-date = 2009-07-17 |
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}}</ref> In contrast to ], trimethylstibine is a weaker ]. It is used in the production of some ]s. |
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}}</ref>. |
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==References== |
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==References== |
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{{organic-compound-stub}} |
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{{organic-compound-stub}}{{Antimony compounds}} |