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'''R-phrases''' are defined in Annex III of ] ]: ''Nature of special risks attributed to dangerous substances and preparations''. The list was consolidated and republished in , where translations into other EU languages may be found. '''R-phrases''' are defined in Annex III of ] ]: ''Nature of special risks attributed to dangerous substances and preparations''. The list was consolidated and republished in , where translations into other EU languages may be found.


*R1: Explosive when dry *{{R1}}: Explosive when dry
*R2: Risk of explosion by shock, friction, fire or other sources of ignition *{{R2}}: Risk of explosion by shock, friction, fire or other sources of ignition
*R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition *{{R3}}: Extreme risk of explosion by shock, friction, fire or other sources of ignition
*R4: Forms very sensitive explosive metallic compounds *{{R4}}: Forms very sensitive explosive metallic compounds
*R5: Heating may cause an explosion *{{R5}}: Heating may cause an explosion
*R6: Explosive with or without contact with air *{{R6}}: Explosive with or without contact with air
*R7: May cause fire *{{R7}}: May cause fire
*R8: Contact with combustible material may cause fire *{{R8}}: Contact with combustible material may cause fire
*R9: Explosive when mixed with combustible material *{{R9}}: Explosive when mixed with combustible material
*R10: Flammable *{{R10}}: Flammable
*R11: Highly flammable *{{R11}}: Highly flammable
*R12: Extremely flammable *{{R12}}: Extremely flammable
*R14: Reacts violently with water *{{R14}}: Reacts violently with water
*R15: Contact with water liberates extremely flammable gases *{{R15}}: Contact with water liberates extremely flammable gases
*R16: Explosive when mixed with oxidising substances *{{R16}}: Explosive when mixed with oxidising substances
*R17: Spontaneously flammable in air *{{R17}}: Spontaneously flammable in air
*R18: In use, may form flammable/explosive vapour-air mixture *{{R18}}: In use, may form flammable/explosive vapour-air mixture
*R19: May form explosive peroxides *{{R19}}: May form explosive peroxides
*R20: Harmful by inhalation *{{R20}}: Harmful by inhalation
*R21: Harmful in contact with skin *{{R21}}: Harmful in contact with skin
*R22: Harmful if swallowed *{{R22}}: Harmful if swallowed
*R23: Toxic by inhalation *{{R23}}: Toxic by inhalation
*R24: Toxic in contact with skin *{{R24}}: Toxic in contact with skin
*R25: Toxic if swallowed *{{R25}}: Toxic if swallowed
*R26: Very toxic by inhalation *{{R26}}: Very toxic by inhalation
*R27: Very toxic in contact with skin *{{R27}}: Very toxic in contact with skin
*R28: Very toxic if swallowed *{{R28}}: Very toxic if swallowed
*R29: Contact with water liberates toxic gas. *{{R29}}: Contact with water liberates toxic gas.
*R30: Can become highly flammable in use *{{R30}}: Can become highly flammable in use
*R31: Contact with acids liberates toxic gas *{{R31}}: Contact with acids liberates toxic gas
*R32: Contact with acids liberates very toxic gas *{{R32}}: Contact with acids liberates very toxic gas
*R33: Danger of cumulative effects *{{R33}}: Danger of cumulative effects
*R34: Causes burns *{{R34}}: Causes burns
*R35: Causes severe burns *{{R35}}: Causes severe burns
*R36: Irritating to eyes *{{R36}}: Irritating to eyes
*R37: Irritating to respiratory system *{{R37}}: Irritating to respiratory system
*R38: Irritating to skin *{{R38}}: Irritating to skin
*R39: Danger of very serious irreversible effects *{{R39}}: Danger of very serious irreversible effects
*R40: Limited evidence of a carcinogenic effect *{{R40}}: Limited evidence of a carcinogenic effect
*R41: Risk of serious damage to eyes *{{R41}}: Risk of serious damage to eyes
*R42: May cause sensitisation by inhalation *{{R42}}: May cause sensitisation by inhalation
*R43: May cause sensitisation by skin contact *{{R43}}: May cause sensitisation by skin contact
*R44: Risk of explosion if heated under confinement *{{R44}}: Risk of explosion if heated under confinement
*R45: May cause cancer *{{R45}}: May cause cancer
*R46: May cause heritable genetic damage *{{R46}}: May cause heritable genetic damage
*R48: Danger of serious damage to health by prolonged exposure *{{R48}}: Danger of serious damage to health by prolonged exposure
*R49: May cause cancer by inhalation *{{R49}}: May cause cancer by inhalation
*R50: Very toxic to aquatic organisms *{{R50}}: Very toxic to aquatic organisms
*R51: Toxic to aquatic organisms *{{R51}}: Toxic to aquatic organisms
*R52: Harmful to aquatic organisms *{{R52}}: Harmful to aquatic organisms
*R53: May cause long-term adverse effects in the aquatic environment *{{R53}}: May cause long-term adverse effects in the aquatic environment
*R54: Toxic to flora *{{R54}}: Toxic to flora
*R55: Toxic to fauna *{{R55}}: Toxic to fauna
*R56: Toxic to soil organisms *{{R56}}: Toxic to soil organisms
*R57: Toxic to bees *{{R57}}: Toxic to bees
*R58: May cause long-term adverse effects in the environment *{{R58}}: May cause long-term adverse effects in the environment
*R59: Dangerous for the ozone layer *{{R59}}: Dangerous for the ozone layer
*R60: May impair fertility *{{R60}}: May impair fertility
*R61: May cause harm to the unborn child *{{R61}}: May cause harm to the unborn child
*R62: Possible risk of impaired fertility *{{R62}}: Possible risk of impaired fertility
*R63: Possible risk of harm to the unborn child *{{R63}}: Possible risk of harm to the unborn child
*R64: May cause harm to breast-fed babies *{{R64}}: May cause harm to breast-fed babies
*R65: Harmful: may cause lung damage if swallowed *{{R65}}: Harmful: may cause lung damage if swallowed
*R66: Repeated exposure may cause skin dryness or cracking *{{R66}}: Repeated exposure may cause skin dryness or cracking
*R67: Vapours may cause drowsiness and dizziness *{{R67}}: Vapours may cause drowsiness and dizziness
*R68: Possible risk of irreversible effects *{{R68}}: Possible risk of irreversible effects
*R14/15: Reacts violently with water, liberating extremely flammable gases *{{R14/15}}: Reacts violently with water, liberating extremely flammable gases
*R15/29: Contact with water liberates toxic, extremely flammable gases *{{R15/29}}: Contact with water liberates toxic, extremely flammable gases
*R20/21: Harmful by inhalation and in contact with skin *{{R20/21}}: Harmful by inhalation and in contact with skin
*R20/22: Harmful by inhalation and if swallowed *{{R20/22}}: Harmful by inhalation and if swallowed
*R20/21/22: Harmful by inhalation, in contact with skin and if swallowed *{{R20/21/22}}: Harmful by inhalation, in contact with skin and if swallowed
*R21/22: Harmful in contact with skin and if swallowed *{{R21/22}}: Harmful in contact with skin and if swallowed
*R23/24: Toxic by inhalation and in contact with skin *{{R23/24}}: Toxic by inhalation and in contact with skin
*R23/25: Toxic by inhalation and if swallowed *{{R23/25}}: Toxic by inhalation and if swallowed
*R23/24/25: Toxic by inhalation, in contact with skin and if swallowed *{{R23/24/25}}: Toxic by inhalation, in contact with skin and if swallowed
*R24/25: Toxic in contact with skin and if swallowed *{{R24/25}}: Toxic in contact with skin and if swallowed
*R26/27: Very toxic by inhalation and in contact with skin *{{R26/27}}: Very toxic by inhalation and in contact with skin
*R26/28: Very toxic by inhalation and if swallowed *{{R26/28}}: Very toxic by inhalation and if swallowed
*R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed *{{R26/27/28}}: Very toxic by inhalation, in contact with skin and if swallowed
*R27/28: Very toxic in contact with skin and if swallowed *{{R27/28}}: Very toxic in contact with skin and if swallowed
*R36/37: Irritating to eyes and respiratory system *{{R36/37}}: Irritating to eyes and respiratory system
*R36/38: Irritating to eyes and skin *{{R36/38}}: Irritating to eyes and skin
*R36/37/38: Irritating to eyes, respiratory system and skin *{{R36/37/38}}: Irritating to eyes, respiratory system and skin
*R37/38: Irritating to respiratory system and skin *{{R37/38}}: Irritating to respiratory system and skin
*R39/23: Toxic: danger of very serious irreversible effects through inhalation *{{R39/23}}: Toxic: danger of very serious irreversible effects through inhalation
*R39/24: Toxic: danger of very serious irreversible effects in contact with skin *{{R39/24}}: Toxic: danger of very serious irreversible effects in contact with skin
*R39/25: Toxic: danger of very serious irreversible effects if swallowed *{{R39/25}}: Toxic: danger of very serious irreversible effects if swallowed
*R39/23/24: Toxic: danger of very serious irreversible effects through inhalation and in contact with skin *{{R39/23/24}}: Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
*R39/23/25: Toxic: danger of very serious irreversible effects through inhalation and if swallowed *{{R39/23/25}}: Toxic: danger of very serious irreversible effects through inhalation and if swallowed
*R39/24/25: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed *{{R39/24/25}}: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
*R39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed *{{R39/23/24/25}}: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
*R39/26: Very Toxic: danger of very serious irreversible effects through inhalation *{{R39/26}}: Very Toxic: danger of very serious irreversible effects through inhalation
*R39/27: Very Toxic: danger of very serious irreversible effects in contact with skin *{{R39/27}}: Very Toxic: danger of very serious irreversible effects in contact with skin
*R39/28: Very Toxic: danger of very serious irreversible effects if swallowed *{{R39/28}}: Very Toxic: danger of very serious irreversible effects if swallowed
*R39/26/27: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin *{{R39/26/27}}: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
*R39/26/28: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed *{{R39/26/28}}: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
*R39/27/28: Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed *{{R39/27/28}}: Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
*R39/26/27/28: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed *{{R39/26/27/28}}: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
*R42/43: May cause sensitisation by inhalation and skin contact *{{R42/43}}: May cause sensitisation by inhalation and skin contact
*R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation *{{R48/20}}: Harmful: danger of serious damage to health by prolonged exposure through inhalation
*R48/21: Harmful: danger of serious damage to health by prolonged exposure in contact with skin *{{R48/21}}: Harmful: danger of serious damage to health by prolonged exposure in contact with skin
*R48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed *{{R48/22}}: Harmful: danger of serious damage to health by prolonged exposure if swallowed
*R48/20/21: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin *{{R48/20/21}}: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
*R48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed *{{R48/20/22}}: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
*R48/21/22: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed *{{R48/21/22}}: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
*R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed *{{R48/20/21/22}}: Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
*R48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation *{{R48/23}}: Toxic: danger of serious damage to health by prolonged exposure through inhalation
*R48/24: Toxic: danger of serious damage to health by prolonged exposure in contact with skin *{{R48/24}}: Toxic: danger of serious damage to health by prolonged exposure in contact with skin
*R48/25: Toxic: danger of serious damage to health by prolonged exposure if swallowed *{{R48/25}}: Toxic: danger of serious damage to health by prolonged exposure if swallowed
*R48/23/24: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin *{{R48/23/24}}: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
*R48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed *{{R48/23/25}}: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
*R48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed *{{R48/24/25}}: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
*R48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed *{{R48/23/24/25}}: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
*R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment *{{R50/53}}: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
*R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment *{{R51/53}}: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
*R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment *{{R52/53}}: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
*R68/20: Harmful: possible risk of irreversible effects through inhalation *{{R68/20}}: Harmful: possible risk of irreversible effects through inhalation
*R68/21: Harmful: possible risk of irreversible effects in contact with skin *{{R68/21}}: Harmful: possible risk of irreversible effects in contact with skin
*R68/22: Harmful: possible risk of irreversible effects if swallowed *{{R68/22}}: Harmful: possible risk of irreversible effects if swallowed
*R68/20/21: Harmful: possible risk of irreversible effects through inhalation and in contact with skin *{{R68/20/21}}: Harmful: possible risk of irreversible effects through inhalation and in contact with skin
*R68/20/22: Harmful: possible risk of irreversible effects through inhalation and if swallowed *{{R68/20/22}}: Harmful: possible risk of irreversible effects through inhalation and if swallowed
*R68/21/22: Harmful: possible risk of irreversible effects in contact with skin and if swallowed *{{R68/21/22}}: Harmful: possible risk of irreversible effects in contact with skin and if swallowed
*R68/20/21/22: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed *{{R68/20/21/22}}: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed


== See also == == See also ==

Revision as of 20:47, 23 October 2005

R-phrases are defined in Annex III of European Union Directive 67/548/EEC: Nature of special risks attributed to dangerous substances and preparations. The list was consolidated and republished in Directive 2001/59/EC, where translations into other EU languages may be found.

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